Advances in Carbohydrate Chemistry 10

Artikelnummer 10123752

CONTENTS CONTRIBUTORS TO VOLUME 10 v PREFACE vii EDMUND GEORGE VINCENT PERCIVAL xiii The Stereochemistry of Cyclic Derivatives of Carbohydrates BY J. A. MILLS, Department of Biochemistry and General Nutrition, Commonwealth Scientific and Industrial Research Organization, Adelaide, Australia I. Introduction 1 II. Nomenclature and Methods of Illustration 2 III. Steric Requirements of Reactions 2 IV. Fundamental Properties of Rings 3 V. Cyclic Acetals 6 VI. Anhydro Compounds 10 25 Column Chromatography of Sugars and Their Derivatives 46 BY W. W. BINKLEY, Department of Chemistry, The Ohio State University, Columbus, Ohio I. Introduction 55 II. Adsorbents for the Column Chromatography of Sugars, Sugar Alcohols, and Sugar Acids 55 III. Column Chromatography of Sugar Derivatives 66 79 Glycosylamines BY G. P. ELLIS AND JOHN HONEYMAN, Department of Chemistry, King's College, University of London, England I. Introduction 95 II. Nomenclature 95 III. Preparation 95 IV. Physical Properties 96 V. Structure 96 VI. Diacosylamines 97 VII. Dialdose Derivatives of Aldoses 101 VIII. Uses of Glycosylamines 102 IX. Tables of Properties of Glycosylamines 120 121 The Amadori Rearrangement 125 BY JOHN E. HODGE, Northern Utilization Research Branch, Agricultural Research Service, U. S. Department of Agriculture, Peoria, Illinois I. Introduction 169 ix II. Nomenclature 172 III. Scope of the Reaction 173 IV. Experimental Methods 175 V. Mechanism of the Reaction 178 VI. Physical Properties of Amadori Rearrangement Products 182 VII. Chemical Properties of Amadori Rearrangement Products 187 VIII. Proof of Structure of Amadori Rearrangement Products 199 IX. Retroposed and the Future 201 X. Tables of Compounds 203 The Glycosyl Halides and Their Derivatives BY L. J. HAYNES, The University, Edinburgh, Scotland AND F. H. NEWTH, The University, Cambridge, England I. Introduction 207 II. Preparation of Glycosyl Halide Derivatives 207 III. Structure of Glycosyl Halides 209 IV. Properties of Glycosyl Halides 229 V. Reaction Mechanism and Effect of Structure on Reaction Rates 233 VI. Reactions of the Poly-O-acylglycosyl Halides 239 VII. Tables of Properties of Some Glycosyl Halide Derivatives 239 246 The Methyl Ethers of the Aldopentoses and of Rhamnose and Fucose BY GEORGE G. MAHER, Research Laboratories, Clinton Foods Inc., Clinton, Iowa Table I 257 Table II 257 Table III 257 Table IV 261 Table V 262 Table VI 265 Table VII 266 Table VIII 266 268 The Methyl Ethers of D-Galactose 269 BY GEORGE G. MAHER, Research Laboratories, Clinton Foods Inc., Clinton, Iowa Table I 273 Table II 273 Table III 273 Table IV 277 279 Polysaccharides Associated with Wood Cellulose 279 BY W. J. POLGLASE, Department of Biochemistry, University of British Columbia, Vancouver, British Columbia, Canada I. Introduction 283 II. Carbohydrate Constituents of Wood 283 III. Carbohydrates in Wood Cellulose 283 IV. Preparation and Composition of Wood Cellulose 285 V. Fine Structure of Wood Cellulose 287 316 and Associated Polysaccharides 328 The Chemistry of Heparin BY A. B. FOSTER, Chemistry Department, The University, Birmingham, England AND A. J. HUGGARD, Chemistry Department, The University, Birmingham, England AND J. M. WEBBER, Chemistry Department, The Ohio State University, Columbus, Ohio I. Introduction 335 II. Occurrence 336 III. The Discovery of Heparin 336 IV. The Biological Potentiation of Heparin 336 V. The Structure of Heparin 336 VI. The Biological Activity of Heparin 337 VII. The Biosynthesis of Mucopolysaccharides 348 AUTHOR INDEX 350 SUBJECT INDEX 367 CONTENTS OF VOLUMES 1-9 369 391 435