Advances in Carbohydrate Chemistry 19

Numéro d'article 10123761

ADVANCES IN CARBOHYDRATE CHEMISTRY Editor MELVILLE L. WOLFROM Associate Editor R. STUART TIPSON Board of Advisors R. C. HOCKETT C. B. PURVES W. W. PIGMAN ROY L. WHISTLER Board of Advisors for the British Isles E. L. HIRST STANLEY PEAT MAURICE STACEY Volume 19 1964 ACADEMIC PRESS NEW YORK and LONDON Alva Thompson CONTENTS CONTRIBUTORS TO VOLUME 19 v PREFACE vii ALVA THOMPSON 1 Crystal-structure Analysis in Carbohydrate Chemistry G. A. JEFFREY AND R. D. ROSENSTEIN I. Introduction 7 II. Determination of Configuration 7 III. Determination of Conformation 8 IV. Measurement of Bond Lengths and Valency Angles 11 V. Hydrogen Bonding and Molecular Packing 15 19 Infrared Spectroscopy and Carbohydrate Chemistry H. SPEDDING I. Introduction 23 II. Experimental 23 III. Interpretation 27 IV. Applications 33 Nuclear Magnetic Resonance L. D. HALL I. Introduction 51 II. Development and Applications to Carbohydrates 51 III. Experimental Techniques 65 Addendum 82 91 Gas-Liquid Chromatography of Carbohydrate Derivatives C. T. BISHOP I. Introduction 95 II. General Methods 96 III. Classes of Carbohydrate Derivatives 96 IV. Structure and Mobility 105 V. Applications 127 VI. Liquid Phases 129 VII. Conclusions 141 145 ix The Action of Hydrogen Peroxide on Carbohydrates and Related Compounds G. J. MOODY I. Introduction 149 II. Hydrogen Peroxide Without a Catalyst 150 III. Hydrogen Peroxide With a Catalyst 156 IV. Summary 177 3-Deoxyglycosuloses (3-Deoxyhexosones) and the Degradation of Carbohydrates E. F. L. J. ANET I. Introduction 181 II. Nomenclature 182 III. 3-Deoxy-D-erythro-hexosulose 183 IV. Compounds Derived from 3-Deoxy-D-erythro-hexosulose 188 V. Other 3-Deoxyglycosuloses 198 VI. Identification and Determination 199 VII. Significance in the Degradation of Carbohydrates 200 Structure and Some Reactions of Cellulose DAVID M. JONES I. Introduction 219 II. The Crystal Structure of Cellulose 219 III. Fine Structure of Cellulose 221 IV. Reactivity of Cellulose 226 V. Reactions of Cellulose 230 VI. Miscellaneous 244 Wood Hemicelluloses: Part I T. E. TIMELL I. Introduction 247 II. O-Acetyl-4-O-methylglucuronoxylans 251 III. Hardwood Glucomannans 255 IV. Other Hardwood Hemicelluloses 290 The Pneumococcal Polysaccharides M. J. HOW, J. S. BRIMACOMBE, AND M. STACEY I. Introduction 303 II. Structural Studies 303 III. Biosynthesis of Pneumococcal Capsular Polysaccharides 308 Addendum 353 356 AUTHOR INDEX FOR VOLUME 19 359 SUBJECT INDEX FOR VOLUME 19 379 CUMULATIVE AUTHOR INDEX FOR VOLUMES 1-19 400 CUMULATIVE SUBJECT INDEX FOR VOLUMES 1-10 405 ERRATA AND ADDENDUM 415